If a neighbor cannot be reached by means of Neighbor Discovery (ND), you can add a static entry to the ND cache. A static IPv6 ND entry is like a static IPv4 ARP entry.
device(config-if-eth-3/5)# ipv6 neighbor 2001:db8:2678::2 0000.002b.8641
device# configuration terminal
device (config)# interface ethernet 3/5
2001:db8:2678::2
and link-layer address
0000.002b.8641
, reachable through interface ethernet
3/5.device(config-if-eth-3/5)# ipv6 neighbor 2001:db8:2678::2 0000.002b.8641